高等学校化学学报2009，Vol.30Issue(11)：2131-2135,5.
镱(Ⅲ)卟啉配合物的合成、结构表征和近红外光谱研究
Synthesis, Characterization and Near-infrared Photoluminescence of Ytterbium(Ⅲ) Monoporphyrinate Complexes
摘要
Abstract
A series of ytterbium (Ⅲ) monoporphyrinate complexes (2a-2e) , bearing different substituents on meso- or B- position, were synthesized and characterized via UV-Vis, ~1H NMR, high-resolution mass spectra and elemental analysis. The photoluminescent properties of the complexes, especially in the near-infrared region, were studied in detail. Related quantum yield and fluorescence lifetime show that the energy is transferred to the excited state of ytterbium(Ⅲ) ion caused by excitation of the π→π~* transitions of porphyrinate, which led to strong NIR emission. The light-emitting efficiency of the complexes with electron-donating substituents on meso-position is better than that of complexes with electron-withdrawing substituents, while the complex with bromide on B-position possesses the poor ability of light-emitting.关键词
镱卟啉配合物的合成/结构表征/近红外光谱Key words
Synthesis of Ytterbium(Ⅲ) monoporphyrinate complex/ Structure characterization/ Near-infrared spectrum分类
化学化工引用本文复制引用
付世涛,张智,俞开潮,黄伟国,李早英..镱(Ⅲ)卟啉配合物的合成、结构表征和近红外光谱研究[J].高等学校化学学报,2009,30(11):2131-2135,5.基金项目
国家自然科学基金(批准号: 20672082)和华中科技大学博士后科学基金(批准号: 20070051)资助. （批准号: 20672082）
