固体火箭技术2009，Vol.32Issue(5)：531-534,4.
新型中性聚合物键合剂设计与合成
Design and synthesis of a novel neutral polymeric bonding agent
摘要
Abstract
The derivative of tri(2-methyl-2-aziridinyl) phosphine oxide(MAPO) via MAPO and acrylic acid(AA) (only one aziridine ring open) was synthesized. The products were qualitatively analyzed by means of infrared and mass spectrometry and the content of aziridine ring was measured by using of non-aqueous titration method. Meanwhile, through the orthogonal design, the optimum reaction condition was obtained as follows;the mole ratio ( MAPO: AA) is 1.0,the reaction temperature is 70℃ and time is 2.5 h. Subsequently, a novel neutral polymeric bonding agent(NPBA) was polymerized with AN, HEA and the derivative of MAPO. Through the contact angle measurement, the estimation results indicate that the novel NPBA possess better bonding performance with cyclotrimethylene trinitramine(RDX) , cyclotetramethylene tetranitroamine(HMX) , ammonium perchlorate( AP).关键词
中性聚合物键合剂/三-(2-甲基氮丙啶基)氧化膦/黑索金/奥克托金/高氯酸铵/粘接性能预估Key words
neutral polymeric bonding agent/MAPO/RDX/HMX/AP/bond performance estimation分类
航空航天引用本文复制引用
申红光,邓剑如..新型中性聚合物键合剂设计与合成[J].固体火箭技术,2009,32(5):531-534,4.基金项目
国防预研基金(9140A28020506JW3201). （9140A28020506JW3201）
