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一种水性环氧固化剂的合成与性能研究

熊远钦 邓红霞 彭桦 夏新年 李海军 徐伟箭

湖南大学学报(自然科学版)2009,Vol.36Issue(11):53-56,4.
湖南大学学报(自然科学版)2009,Vol.36Issue(11):53-56,4.

一种水性环氧固化剂的合成与性能研究

Synthesis of a Waterborne Epoxy Curing Agent and Its Properties

熊远钦 1邓红霞 1彭桦 1夏新年 1李海军 1徐伟箭1

作者信息

  • 1. 湖南大学,化学化工学院,湖南,长沙,410082
  • 折叠

摘要

Abstract

A waterborne curing agent for epoxy resin was synthesized by using PEG-2000, Triethylene tetramine (TETA) and Bisphenol A didycidyl ether (CYD-128). Firstly, in order to incorporate the hy-drophilic and soft polyether segment into the molecular structure of curing agent, PEG-2000 reacted with CYD-128 with Lewis acid as the catalyst. Secondly, in order to incorporate the epoxy resin molecular chain segment into the molecular structure of curing agent to improve the compatibility of the curing agent with the waterborne epoxy resin, TETA was modified with the product of the first step and low weight epoxy resin . Finally, deionized water was continuously added to adduct up to 50% solid content.

关键词

环氧固化剂/水性涂料/双酚A环氧树脂/聚乙二醇/三乙烯四胺

Key words

epoxy curing agent/ waterbone/ bisphenol A epoxy resin/ polyethylene glycol/ triethylene tetramine

分类

化学化工

引用本文复制引用

熊远钦,邓红霞,彭桦,夏新年,李海军,徐伟箭..一种水性环氧固化剂的合成与性能研究[J].湖南大学学报(自然科学版),2009,36(11):53-56,4.

基金项目

湖南省科技厅科技计划资助项目(2007FJ3020) (2007FJ3020)

湖南大学学报(自然科学版)

OA北大核心CSCDCSTPCD

1674-2974

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