人工晶体学报2009，Vol.38Issue(5)：1272-1275,1279,5.
水热合成超分子网络化合物[Mn(phen)_2I_2] (phen=邻菲咯啉)及晶体结构
Hydrothermal Synthesis and Crystal Structure of a Supramolecular Network [Mn(phen)_2I_2]
摘要
Abstract
A novel supramolecular network [Mn(phen)_2I_2] has been rationally designed and synthesized by hydrothermal method and the structure was characterized with elemental analysis, FT-IR spectrum and X-ray diffractometer. It crystallizes in the Triclinic, space group P_1~-, with a= 0.92705(19) nm,b= 1.0370 (2) nm, c=1.2775(3) nm,α=77.32(3) °, β=81.26(3)°,γ=70.30(3) °,V=1.1240(4) nm~3,Z=2. In the title compound [Mn(phen)_2I_2], the separated unit cells are constructed into a novel supramolecular network by four types of C-H…I hydrogen-bonded and two kinds of π-π interactions.关键词
水热合成/配位键/氢键/π-π堆积作用Key words
hydrothermal synthesis/ coordinate bond/ hydrogen bond/ π-π interactions分类
数理科学引用本文复制引用
马天慧,贾林艳,任玉兰,尹永一,董维广,吕孝江..水热合成超分子网络化合物[Mn(phen)_2I_2] (phen=邻菲咯啉)及晶体结构[J].人工晶体学报,2009,38(5):1272-1275,1279,5.基金项目
黑龙江省教育厅科学技术研究项目(No.10551320) （No.10551320）
