应用化学2009，Vol.26Issue(11)：1324-1327,4.
Keggin型Ni-Mo-Zr杂多酸盐的合成、表征及催化超声降解性能
Synthesis, Characterization of Ni-Mo-Zr Heteropoly Salt with Keggin Structure and Its Ultrasonic Degradation Efficiency
张治宏 1王晓昌 2常哲敏 1吕素娟2
作者信息
- 1. 西安建筑科技大学环境与市政工程学院,西安,710055
- 2. 西安工业大学材料与化工学院,西安
- 折叠
摘要
Abstract
The Ni-Mo-Zr heteropoly salt with Keggin structure has been hydrothermally synthesized and characterized by IR and XRD. Efficiency of ultrasonic degradation of the heteropoly salt for the acidic-green B (AGB) dye as the objective compound was investigated, and the influence factors on the ultrasonic degradation efficiency, such as the amount of the heteropoly salt, the initial concentration and the pH value of the acidic-green B dye wastewater, were explored. The results show that newly synthesized Ni-Mo-Zr heteropoly salt had Keggin structure. When the amount of the heteropoly salt was 0. 8 g/L, the initial concentration of the dye wastewater was 10 mg/L and the initial pH value of the wastewater was 5.0, and ultrasonic irradiation was carried out for 60 min at 40 kHz, the degradation rate was optimum and up to 90.2%. After dynamics analysis, it showed the degradation reaction was in accord with the first order dynamics model, and the degradation rate was decreased with the increasing of the initial concentration of the acidic-green B.关键词
Ni-Mo-Zr/Keggin结构/杂多酸盐/超声降解/酸性绿B/废水处理Key words
Ni-Mo-Zr/ Keggin structure/ heteropoly salt/ ultrasonic degradation/ acidic-green B/ wastewater treatment分类
化学化工引用本文复制引用
张治宏,王晓昌,常哲敏,吕素娟..Keggin型Ni-Mo-Zr杂多酸盐的合成、表征及催化超声降解性能[J].应用化学,2009,26(11):1324-1327,4.
