应用化学2009，Vol.26Issue(10)：1189-1193,5.
含有3H-苯并吡喃-2-酮骨架化合物的液晶性和凝胶性能
Liquid Crystal and Gelation Properties of Compounds with a Chromen-2-one Skeleton
朱琳 1张福胜2
作者信息
- 1. 吉林化工学院,分析中心,吉林,132022
- 2. 吉林化工学院,化工与材料工程学院,吉林,132022
- 折叠
摘要
Abstract
4-Alkoxy-biphenyl-4′-carboxy-lates(2-n) was synthesized by introducing a benzyl ring on the side of alkoxy chain of chromen-2-one-6-yl 4-alkoxy benzoates(1-n). The liquid crystalline and gelation of compound 2-n were determined. Comparing with compound 1-n, compound 2-n exhibits enantiotropic nematic phase and can form gels with various organic solvents. The critical gel concentrations in various solvents were determined and the three-dimensional network structure consisting of xerogel fibrils was observed with a scanning electron microscope. Conclusively, intermolecular interactions around lactone moiety having a broad shape and a large dipole moment play important roles in enhancing the broad gelling ability.关键词
液晶/凝胶/胶凝化/苯并吡喃-酮/干凝胶/小分子有机凝胶剂Key words
liquid crystals/gel/gelation/chromen-one/xerogel/low molecular mass organic gelators分类
化学化工引用本文复制引用
朱琳,张福胜..含有3H-苯并吡喃-2-酮骨架化合物的液晶性和凝胶性能[J].应用化学,2009,26(10):1189-1193,5.
