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可溶性苝四羧酸二酰亚胺发光材料的合成及表征

徐业伟 朱方华 张海连 王鹏 张林

应用化学2009,Vol.26Issue(11):1269-1272,4.
应用化学2009,Vol.26Issue(11):1269-1272,4.

可溶性苝四羧酸二酰亚胺发光材料的合成及表征

Synthesis and Characterization of Soluble Perylene Diimide Light-emitting Materials

徐业伟 1朱方华 2张海连 2王鹏 2张林1

作者信息

  • 1. 西南科技大学,材料科学与工程学院,绵阳
  • 2. 中国工程物理研究院,激光聚变研究中心,绵阳,621900
  • 折叠

摘要

Abstract

Perylene derivatives PeryBr_2, DD-PeryBr_2 and DD-PeryBp_2 were synthesized from perylene-3,4,9, 10-tetracarboxylic acid bisanhydride and characterized by UV-Vis, FT-IR, ~1H NMR, MS, TGA and fluorescence spectroscopy measurements. The result shows that DD-PeryBp_2 is highly soluble in conventional solvents such as toluene, chloroform and THF. The UV-Vis maximal absorption and fluorescence spectroscopy maximal emission of DD-PeryBp_2 are at 548 nm and 576 nm, respectively. TG measurements show that perylene diimides possess good thermal stability and the temperature at which 5% mass loss is observed in nitrogen is 433 ℃.

关键词

苝四羧酸二酰亚胺/溶解性/热稳定性/发光材料

Key words

perylene diimides/solubility/thermal stability/light-emitting material

分类

化学化工

引用本文复制引用

徐业伟,朱方华,张海连,王鹏,张林..可溶性苝四羧酸二酰亚胺发光材料的合成及表征[J].应用化学,2009,26(11):1269-1272,4.

基金项目

中国工程物理研究院高温高密度等离子体物理国防科技重点实验室基金(9140C6806040611)资助项目 (9140C6806040611)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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