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ZrCl_4蒸汽沉积法制备高温气冷堆包覆燃料颗粒ZrC涂层

陈磊 刘超 刘兵 赵宏生 唐春和

原子能科学技术2009,Vol.43Issue(11):1017-1020,4.
原子能科学技术2009,Vol.43Issue(11):1017-1020,4.

ZrCl_4蒸汽沉积法制备高温气冷堆包覆燃料颗粒ZrC涂层

Preparation of ZrC Layer of Coated Fuel Particle for High-Temperature Gas-Cooled Reactor by Chemical Vapor Deposition With ZrCl_4 Vapor

陈磊 1刘超 1刘兵 1赵宏生 1唐春和1

作者信息

  • 1. 清华大学,核能与新能源技术研究院,北京,100084
  • 折叠

摘要

Abstract

The ZrC layer of coated fuel particle was successfully prepared in the fluidized bed coating furnace by chemical vapor deposition, using a gas mixture of C_3H_6, ZrCl_4 vapor, H_2 and Ar. It is indicated that the deposited ZrC layer has smooth and compact surface without obvious holes, clear interfaces with inner dense pyrocarbon layer, thickness of 35 μm. Composition and crystal structure analyses indicate that the main elements of ZrC layer are Zr and C, and the Zr/C molar ratio is close to 1:1. Stoichiomet-ric fcc-ZrC was obtained. And non-preferred orientation of grains was observed.

关键词

ZrCl_4蒸汽/化学气相沉积/包覆燃料颗粒/ZrC涂层

Key words

ZrCl_4 vapor/ chemical vapor deposition/ coated fuel particle/ ZrC layer

分类

能源科技

引用本文复制引用

陈磊,刘超,刘兵,赵宏生,唐春和..ZrCl_4蒸汽沉积法制备高温气冷堆包覆燃料颗粒ZrC涂层[J].原子能科学技术,2009,43(11):1017-1020,4.

原子能科学技术

OA北大核心CSCDCSTPCD

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