硅酸盐学报2011，Vol.39Issue(8)：1235-1238,4.
BaMg2-x（PO4）2：xEu^3＋橙红色荧光粉的制备及发光性质
Preparation and Luminescence Properties of BaMg2-x（PO4）2：xEu^3＋ Salmon Pink-Emitting Phosphor
摘要
Abstract
BaMg2–x（PO4）2：xEu^3＋ phosphors were synthesized by a high temperature solid state method.The result by X-ray diffraction（XRD） indicates that the sample is a pure phase of BaMg2（PO4）2 crystal structure.The photoluminescence spectra exhibits that the sample fitted a ultraviolet–light emitting diode（UV–LED） chip（350–410 nm） excitation.The main emission peaks locates at 595 nm（^5D0→7F1）,614 nm（^5D0→7F2） and 700 nm（^5D0→^7F4）.The results show that the transition of 5D0→7F1 is enhanced and the transition of ^5D0→^7F2 is inhibited when the amount of Eu^3＋-doped in the BaMg2–x（PO4）2：xEu^3＋ is increased.The charge compensation results show that incorporation of Li＋,Na＋ and K＋ could increase the emission intensity.It was found that Li＋ ion could give the best im-provements of the intensity of 595 nm and K＋ ion to the intensity of 614 nm.The increase of the compensation ionic radius could increase the probability of electric dipole allowed ^5D0→^7F2 transition.关键词
磷酸镁钡/荧光粉/光致发光/发光二极管/电荷补偿Key words
barium magnesium phosphate/phosphors/photoluminescence/light emitting diode/charge compensation分类
物理学引用本文复制引用
杨志平,周东站,韩月,马淑媛,宋延春,于红伟..BaMg2-x（PO4）2：xEu^3＋橙红色荧光粉的制备及发光性质[J].硅酸盐学报,2011,39(8):1235-1238,4.基金项目
河北省自然科学基金(F2009000217)资助项目. （F2009000217）
