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臭氧氧化法降解浮选废水中残余BK809

米丽平 孙春宝 徐涛 赵留成 王彪 罗盛康

北京科技大学学报2011,Vol.33Issue(8):916-921,6.
北京科技大学学报2011,Vol.33Issue(8):916-921,6.

臭氧氧化法降解浮选废水中残余BK809

Degradation of residual BK809 in flotation wastewater by ozonation

米丽平 1孙春宝 1徐涛 1赵留成 1王彪 1罗盛康1

作者信息

  • 1. 北京科技大学土木与环境工程学院,北京100083
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摘要

Abstract

Ozonation was used to degrade residual BK809 in flotation wastewater and the degraded products in different stages were identified and quantified by gas chromatography-mass spectrometry(GC-MS).The results showed that the COD removal rate of 68.68% could achieve at an ozone flow rate of 300mg·h-1 for 20min and pH 9-11.It was indicated from GC-MS analysis that BK809 was firstly oxidized to azobenzene and then converted to nitrobenzene.With the deepening of ozonation,the benzene was broken and further decomposed into C15-C25 carbon-chain alkanes and gaseous substances,including nitrogen oxides and carbon oxides.Finally the residual mass percentage of total organic compounds(TOC) reduced from 100.00% to 17.18%.Meantime,the chroma of the wastewater increased from 5.02 to 471.71 and then decreased to 28.75;in macroscopic view,the color of the wastewater turned from colorless to brown,and then from brown to milky.

关键词

浮选/废水处理/臭氧氧化/降解

Key words

flotation/wastewater treatment/ozonation/degradation

分类

资源环境

引用本文复制引用

米丽平,孙春宝,徐涛,赵留成,王彪,罗盛康..臭氧氧化法降解浮选废水中残余BK809[J].北京科技大学学报,2011,33(8):916-921,6.

北京科技大学学报

OA北大核心CSCDCSTPCD

2095-9389

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