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含磷聚酰亚胺薄膜在原子氧环境中的降解研究

李卓 宋海旺 刘金刚 杨海霞 杨士勇

航天器环境工程2011,Vol.28Issue(3):228-232,5.
航天器环境工程2011,Vol.28Issue(3):228-232,5.DOI:10.3969/j.issn.1673-1379.2011.03.004

含磷聚酰亚胺薄膜在原子氧环境中的降解研究

Degradation of phosphorus-containing polyimides in atomic oxygen environment

李卓 1宋海旺 1刘金刚 1杨海霞 1杨士勇1

作者信息

  • 1. 中国科学院化学研究所高技术材料实验室,北京100190
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摘要

Abstract

The degradation of phosphorus-containing polyimide (PI) films in the simulated atom oxygen environment is investigated using the samples developed in our laboratory. The test results from scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) indicate that the phosphorous and oxygen element contents in the PI film surfaces are increased significantly after the atomic oxygen irradiation; meanwhile, the binding energies are increased at the same time, which suggests that a surface layer of phosphorus oxide is formed to inhibit the further erosion of the underlined PI film surface. Thus, the present PI films exhibit a good atomic oxygen resistance, whose mass loss rates are much lower than that of the Kapton film.

关键词

聚酰亚胺/原子氧/辐照试验/降解

Key words

polyimide/ atomic oxygen/ irradiation test/ degradation

分类

航空航天

引用本文复制引用

李卓,宋海旺,刘金刚,杨海霞,杨士勇..含磷聚酰亚胺薄膜在原子氧环境中的降解研究[J].航天器环境工程,2011,28(3):228-232,5.

基金项目

国家自然科学基金资助(项目编号:50403025),中国科学院化学研究所分子科学中心资助(项目编号:CMS-LX201003) (项目编号:50403025)

航天器环境工程

OACSTPCD

1673-1379

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