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疏水缔合聚合物在石英砂表面的吸附——疏水基含量和微嵌段长度对吸附的影响

柳建新 周薇 刘义刚 郭拥军 冯茹森 舒炼

应用化学2011,Vol.28Issue(7):785-790,6.
应用化学2011,Vol.28Issue(7):785-790,6.DOI:10.3724/SP.J.1095.2011.00531

疏水缔合聚合物在石英砂表面的吸附——疏水基含量和微嵌段长度对吸附的影响

Adsorption of Hydrophobically Associating Polymer on Sand:Influence of Hydrophobe Content and Micro-block Length

柳建新 1周薇 2刘义刚 3郭拥军 1冯茹森 1舒炼1

作者信息

  • 1. 西南石油大学,油气藏地质及开发工程国家重点实验室,成都,610500
  • 2. 中国海洋石油总公司,海洋石油高效开发国家重点实验室,北京
  • 3. 中海石油(中国)有限公司天津分公司,天津
  • 折叠

摘要

Abstract

The static adsorption properties of several water soluble polymers, including different kinds of partially hydrolyzed polyacryamide ( HPAM ) and hydrophobically associative water soluble polymers (HAWSPs), have been studied at 45 ℃, 55 ℃ and 65 ℃. The results show that the maximum adsorption of HAWSPs on sand is affected by the hydrophobe contents and the lengths of micro-block, with the former one playing the major role. The isothermal adsorption curves show two platform areas. The maximum adsorption of HPAM rises with the increase of temperature, but the situation for HAWSPs is in the contrary. It indicates that the hydrophobe contents and the lengths of micro-block may affect the adsorption.

关键词

疏水缔合聚合物/微嵌段共聚物/静态吸附/最大吸附量/等温吸附/吸附焓

Key words

hydrophobically associative water soluble polymer/ micro-block copolymer/ static adsorption/ maximum adsorption/ isothermal adsorption/ adsorption enthalpy

分类

化学化工

引用本文复制引用

柳建新,周薇,刘义刚,郭拥军,冯茹森,舒炼..疏水缔合聚合物在石英砂表面的吸附——疏水基含量和微嵌段长度对吸附的影响[J].应用化学,2011,28(7):785-790,6.

基金项目

国家高技术研究发展计划(863计划)(2007AA090701-1)资助项目 (863计划)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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