火炸药学报2011，Vol.34Issue(3)：28-31,4.
双胍基均四嗪硝基酚高氮盐的合成、热分解和感度
Synthesis,Thermal Decomposition and Sensitivity Properties of a Series of Salts of Di-guanidine-s-tetrazine of Nitro-phenol
摘要
Abstract
Tri-nitro-phenol(PA) . Tri-nitro-resorcinol(TNR) and tri-nitro-phloroglucinol(TNPG) salts of 3, 6-digua-nidino-s-tetrazine(DGTz) were synthesized by reacting DGTz with PA, TNR and TNPG respectively. Thermal decomposition characters of the title compounds were investigated by DSC and TG-DTG. At 10℃ ? Min-1 linear heating rate, the thermal decomposition processes of those salts showed that there was only one exothermic peak for each salt between 50 -450℃ , and the title compounds were completely decomposed without any residue at 600℃. The kinetic parameters of the exothermic process of the title compounds were calculated by Kissinger's method and Oza-wa-Doyle's method, and the Arrhenius equations were obtained. Conventional sensitivity properties were determined ,showing that the three salts were insensitive to friction, impact and flame.关键词
有机化学/双胍基均四嗪硝基酚盐/有机合成/热分解/非等温反应动力学/感度性质Key words
organic chemistry/nitrophenol salt of di-guanidine-s-tetrazine/organic synthesis/thermal descomposition/non-isothemal kinetic/sensitivity property分类
军事科技引用本文复制引用
梁彦会,张建国,谢少华,张同来,舒远杰,杨利,周遵宁..双胍基均四嗪硝基酚高氮盐的合成、热分解和感度[J].火炸药学报,2011,34(3):28-31,4.基金项目
国家自然科学基金委员会一中国工程物理研究院联合基金资助项目(NSAF No.10776002) （NSAF No.10776002）
教育部新世纪优秀人才资助计划项目(CNET-09-0051) （CNET-09-0051）
