火炸药学报2011，Vol.34Issue(3)：12-14,20,4.
1,5-二叠氮基-3-硝基氮杂戊烷合成反应动力学
Synthesis Reaction Kinetics of 1,5-Diazido-3-nitrazapentane
高福磊 1姬月萍 1汪伟 1刘卫孝 1陈斌 1刘亚静 1丁峰1
作者信息
- 1. 西安近代化学研究所,陕西西安710065
- 折叠
摘要
Abstract
1,5-Diazido-3-nitrazapentane was synthesized using diethylnitramine dinitrate and sodium azide as starting materials. The kinetic equation describing the synthesis reaction was established. The effect of temperature on the reaction rate was studied. The results indicate that the reaction is of the second order under the experimental conditions, rate constants of the reaction at the temperature of 90,93,95 and 98℃ are 2. 11×103,4. 72×103,6. 55×103, 1.20×102dm3 ? Mol-1 ? Min-1, respectively. The apparent activation energy E, and pre-exponential factor A of this reaction are 28. 87 Kj ? Mol-1 and 7. 67×1031 min-1, respectively.关键词
物理化学/反应动力学/1,5-二叠氮基-3-硝基氮杂戊烷/DIANPKey words
physical chemistry/reaction kinetics/1,5-diazido-3-nitrazapentane/DIANP分类
军事科技引用本文复制引用
高福磊,姬月萍,汪伟,刘卫孝,陈斌,刘亚静,丁峰..1,5-二叠氮基-3-硝基氮杂戊烷合成反应动力学[J].火炸药学报,2011,34(3):12-14,20,4.
