南京林业大学学报（自然科学版）2011，Vol.35Issue(4)：87-90,4.DOI:10.3969/j.issn.1000-2006.2011.04.018
精馏法催化大豆油裂解制备可再生燃料油
Catalytic cracking of soybean oil via a distillation process for renewable liquid fuel
摘要
Abstract
The catalytic cracking reactions of soybean oil have been studied using a self-assembled distillation apparatus,and the optimal technological conditions were obtained as follows:the distillation temperature 320-350 ℃,cracking temperature 480-500 ℃,and adding rate of soybean oil 35 g/h.The fraction distribution of product was modified by the basic catalyst such as Na2CO3 and distillation process.It was known from the analysis results of FTIR,GC-MS and SEC that the cracked products mainly consisted of alkanes,alkenes,aldehyde,and carboxylic acid.Furthermore,the cracked-oil had a low average molecular weight,and had similar physical and chemical properties comparing to those specified for petroleum-based fuels.The properties of the cracked oil were measured as follows:density of 825 kg/m3,viscosity of 4.0 mm2/s,calorific value of 42 MJ/kg,freezing point of -9 ℃,and cold filter plugging point of -4 ℃.关键词
催化裂解/精馏工艺/大豆油/可再生燃料Key words
catalytic cracking/ distillation process/ soybean oil/ renewable liquid fuel分类
能源科技引用本文复制引用
陈洁,蒋剑春,徐俊明,聂小安..精馏法催化大豆油裂解制备可再生燃料油[J].南京林业大学学报（自然科学版）,2011,35(4):87-90,4.基金项目
国家高技术研究发展计划(2009AA05Z437) （2009AA05Z437）
国家自然科学基金项目(30671649) （30671649）
江苏省自然科学基金项目(BK2009545) （BK2009545）
国家林业局林业公益性行业科研专项(200904008) （200904008）
“十二五”国家科技支撑计划(2011BAD22B05) （2011BAD22B05）
