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PBO纤维的紫外光老化及防老化研究

宋波 傅倩 刘小云 庄启昕 韩哲文

固体火箭技术Issue(3):378-383,392,7.
固体火箭技术Issue(3):378-383,392,7.

PBO纤维的紫外光老化及防老化研究

Study on the photolysis and stabilization of PBO fiber

宋波 1傅倩 1刘小云 1庄启昕 1韩哲文1

作者信息

  • 1. 华东理工大学,特种功能高分子材料及相关技术教育部重点实验室,上海200237
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摘要

Abstract

The photolysis of PBO fibers exposed to UV light was investigated. The attempts to improve aging resistance of PBO fiber were investigated. It is first time to find that the photolysis of PBO fibers includes two development stages: one could be defined as the physical degradation stage and the other could be defined as the chemical degradation stage. In the physical degradation stage, the main features present that the defects appear on the cortex of fiber, which result in the slow decrease of tensile strength. The chemical degradation stage mainly behaves as chain scission of PBO molecule, which results in the serious damage of fiber surface and sharp reduce of tensile strength. Attempts to improve photo stabilization of PBO fibers, such as improving structure of fiber, coating gel particles on the surface of fiber and using anti-aging agent, were done so that the photo stability of PBO fibers could be improved to some extent by using these methods.

关键词

PBO纤维/光降解/老化行为/光稳定性/耐老化

Key words

PBO fiber/photolysis/aging behavior/photo stability/aging resistance

分类

通用工业技术

引用本文复制引用

宋波,傅倩,刘小云,庄启昕,韩哲文..PBO纤维的紫外光老化及防老化研究[J].固体火箭技术,2011,(3):378-383,392,7.

基金项目

国家自然科学基金项目(50703010和50973028) (50703010和50973028)

固体火箭技术

OA北大核心CSCDCSTPCD

1006-2793

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