物理化学学报2011，Vol.27Issue(8)：1886-1892,7.
磺化聚醚砜/薄水铝石复合质子交换膜的性能
Properties of SPES/AIOOH Composite Proton Exchange Membranes
摘要
Abstract
Novel sulfonated polyether suffone (SPES)/AIOOH organic/inorganic composite membranes were prepared by doping SPES with AIOOH, which lowered the methanol crossover and increased the proton conductivity at high temperatures. The structure and performance of the obtained membranes were characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) etc. Compared with the pure SPES membrane the composite membranes had higher thermal stability and water uptake. The morphology of the composite membranes indicated that AIOOH was uniformly distributed throughout the SPES matrix. The network-like structure began to form when the AIOOH content was around 10%. The proton conductivity was still ca 0.014 S·cm-1 even at a temperature as high as 120 ℃. Additionally, the methanol resistance improved greatly as the content of AIOOH increased. The SPES/AIOOH composite membrane is a promising candidate for direct methanol fuel cell (DMFC) applications.关键词
磺化聚醚砜/AIOOH/复合膜/直接甲醇燃料电池Key words
Sulfonated poly(ethersulfone)/ AIOOH/ Composite membrane/ Direct methanol fuel cell分类
化学化工引用本文复制引用
文胜,龚春丽,蔡芳昌,叶正涛..磺化聚醚砜/薄水铝石复合质子交换膜的性能[J].物理化学学报,2011,27(8):1886-1892,7.基金项目
湖北省自然科学基金(2010CDB00301)资助项目 （2010CDB00301）
