现代科学仪器Issue(3)：111-112,116,3.
YGG晶体中Ru3+离子的缺陷结构和自旋哈密顿参量研究
Study of Defect Structure and Spin-Hamiltonian Parameters for Ru3+ Ions in YGG Crystals
摘要
Abstract
YGG:Ru3+ crystal is an important laser material. On the basis of the crystal field theory and spin Hamilto-nian theory, by using the perturbation formula for the low spin (S=l/2) d5 configuration in strong trigonal field, spin Hamil-tonian parameters (g factors g ?, g ± and A ?, A ±) of Ru3+ ions in YGG crystals were calculated. By fitting the bond angle 0, the covalent parameter N2 and the core polarization constant k, these spin-Hamiltonian parameters were reasonably explained. Furthermore, the defect structure for the Ru3+ center in YGG crystals was obtained to be D3d symmetry, and the defected bond angle was 56.097°.关键词
光谱/电子顺磁共振/晶体场理论/Ru3+离子Key words
Optical spectra/ EPR/ Crystal-field theory/ Ru3+ions分类
数理科学引用本文复制引用
丁军涛,谢林华,刘丽..YGG晶体中Ru3+离子的缺陷结构和自旋哈密顿参量研究[J].现代科学仪器,2011,(3):111-112,116,3.基金项目
四川省教育厅科研基金重点项目(10ZA002) （10ZA002）
