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集中交联硅橡胶硫化体系及其工艺

李艳 芦艾 杨海波

宇航材料工艺2011,Vol.41Issue(4):27-31,5.
宇航材料工艺2011,Vol.41Issue(4):27-31,5.

集中交联硅橡胶硫化体系及其工艺

Curing System and Process of Silicone Rubber With Concentrative Crosslinker

李艳 1芦艾 1杨海波2

作者信息

  • 1. 西南科技大学材料学院,绵阳621010
  • 2. 中国工程物理研究院化工材料研究所,绵阳621900
  • 折叠

摘要

Abstract

The curing characteristics of unvulcanized filled silicone rubber were investigated by a Dynamic Mechanical Thermal Analyzer ( DMTA) called RSA3 instead of curemeters. The influence of curing agent type on the curing characteristics of silicone rubber when choosing polyvinylsilicone oil, namely C gum, as concentrative crosslinker were studied. And the differences of crosslink reactions of rubber with three different curing agents were also discussed. The results show that benzoyl peroxide (BPO) can' t well cure silicone rubber with C gum. While the di-cumyl peroxide (DCP) , one vinyl-specific curing agent, can well cure silicone rubber with C gum. The best cure effect in the presence of concentrative crosslinking of silicone rubber of this research is a combination of DCP and BPO. The silicone rubber cured with the combination of BPO and DCP have high modulus, and the rubber can be cured by two cure stages of low and high cure temperature without cure reactions rate decreasing.

关键词

硅橡胶/硫化剂/多乙烯基硅油/集中交联

Key words

Silicone rubber/Curing agent/Polyvinylsilicone oil/Concentrative crosslink

引用本文复制引用

李艳,芦艾,杨海波..集中交联硅橡胶硫化体系及其工艺[J].宇航材料工艺,2011,41(4):27-31,5.

基金项目

中国工程物理研究院科学技术发展基金重点项目(2008 A0302011) (2008 A0302011)

宇航材料工艺

OA北大核心CSCDCSTPCD

1007-2330

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