安徽大学学报（自然科学版）2011，Vol.35Issue(4)：79-85,7.
聚(丁二酸丁二醇酯己内酯)的扩链改性研究
Studies on chain extension modification of PBSCL
摘要
Abstract
In this thesis, a series of biodegradable chain extended copolymers were synthesized by melt polycondensation from succinic acid, 1,4-butanediol, e-caprolactone and TDI. The chemical structure was characterized by Fourier transform infrared spectroscopic (FT-IR) and hydrogen nuclear magnetic resonance 8pectrum('H-NMR).The differential scanning calorimetry(DSC) test showed that the copolymers have good thermal properties, PBSCL had a decrease in melting point with the increasing content of e-caprolactone. Also, the effects of temperature of the extended reaction and feed molar ratio on the inherent viscosity of copolymers were studied. The results of hydrolytic degradation showed that the rate of biodegradation of copolymers was faster in acid solution.关键词
聚丁二酸丁二醇酯/ε-己内酯/热性能/水降解/扩链改性Key words
poly(butylene succinate)/ e-caprolactone/ thermal property/ hydrolytic degradation/ chain extension modification分类
化学化工引用本文复制引用
郝瑞,余瑾,周艺峰,聂王焰..聚(丁二酸丁二醇酯己内酯)的扩链改性研究[J].安徽大学学报（自然科学版）,2011,35(4):79-85,7.基金项目
安徽省高等学校自然科学研究基金重点资助项目(KJ2009A51) （KJ2009A51）
安徽大学“211工程”三期建设学术创新团队经费资助项目 （）
