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一种双尾双季铵盐表面活性剂的合成及其性能

钟声 刘学立

日用化学工业2011,Vol.41Issue(4):235-239,5.
日用化学工业2011,Vol.41Issue(4):235-239,5.

一种双尾双季铵盐表面活性剂的合成及其性能

Synthesis and properties of a kind of two tailed bisquaternary ammonium salt surfactant

钟声 1刘学立1

作者信息

  • 1. 辽宁科技大学化学工程学院,辽宁 鞍山114051
  • 折叠

摘要

Abstract

A kind of two tailed bisquaternary ammonium salt surfactant was prepared by Hofmann alkylation and quaterisation with bromododecane as starting material. Active matter content of the product was examined by bromophenol blue two - phase titration method, which reaches 98. 11%. The structure of the target product was characterized by IR and HNMR. The surface activity of aqueous solution of the product at 55 t was measured as cmc =0. 50 mmol· L-l ,and ycmc =28.95 mN · m-1. The antimicrobial performance of the two tailed product was examined. Results showed that the product exhibits outstanding bacleriostatic properties against Nitrogen - fixing bacteria, Nitrobacteria, Staphylococcus aureus, Cladosporium, Bacillus cereus and Pseudomonas aeruginosa. Acute toxicity test result of the product showed that the product is a sort of low toxicity compound.

关键词

表面活性剂/双季铵盐/双尾/抑菌性能/低毒

Key words

surfactant/bisquaternary ammonium salt/two tailed/bacteriostatic property/low toxicity

分类

化学化工

引用本文复制引用

钟声,刘学立..一种双尾双季铵盐表面活性剂的合成及其性能[J].日用化学工业,2011,41(4):235-239,5.

基金项目

辽宁省教育厅重点实验室资助项目(20095059) (20095059)

日用化学工业

OA北大核心CSCDCSTPCD

1001-1803

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