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添加剂对电镀锌稀土转化膜成膜作用机理的研究

章江洪 张英杰

材料工程Issue(5):48-52,5.
材料工程Issue(5):48-52,5.

添加剂对电镀锌稀土转化膜成膜作用机理的研究

Effects of Additives on Formation Interaction Mechanism of Rare Earth Conversion Coating of Zinc Plating

章江洪 1张英杰2

作者信息

  • 1. 昆明理工大学理学院,昆明,650093
  • 2. 昆明理工大学,冶金与能源工程学院,昆明,650093
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摘要

Abstract

It was of great significance to the efficient formation of rare earth conversion coating with high corrosion resistance by using chemical immersion method through the addition of oxidant and promoter of coating-formation for the preparation of rare earth conversion coating on the surface of zinc plating. The results show that through the electrochemistry test, morphology analysis and dynamics data calculation, reductive reaction at micro-cathode is speeded up by the addition of oxidant H2O2 into the treatment solution, and promoting the increase of Ph within the micro-cathode region, which is favorable to the formation of conversion coating with high content of Ce. The addition of coating-formation promoter can improve the shape quality of the coating, whose essence is to lower effectively the apparent activation energy for coating-formation reaction with three stages,giving rise to the realization of promotion for conversion coating's growing.

关键词

氧化剂/成膜促进剂/稀土转化膜/成膜机理

Key words

oxidant/ accelerator/ rare earth conversion coating/ formation mechanism

分类

矿业与冶金

引用本文复制引用

章江洪,张英杰..添加剂对电镀锌稀土转化膜成膜作用机理的研究[J].材料工程,2011,(5):48-52,5.

材料工程

OA北大核心CSCDCSTPCD

1001-4381

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