色谱2011，Vol.29Issue(6)：563-566,4.DOI:10.3724/SP.J.1123.2011.00563
气相色谱-串联质谱法测定土壤中的邻苯二甲酸酯
Determination of phthalic acid esters in soil by gas chromatography-tandem mass spectrometry
摘要
Abstract
A method based on gas chromatography-tandem mass spectrometry (GC-MS/MS) was developed for the determination of phthalic acid esters (PAEs) in soil. The soil sample was extracted by dichloromethane-acetone (1:1, v/v) with an ultrasonic instrument, and the extract was cleaned up with a Florisil column. The identification and quantification of the ana-lytes were carried out in the multiple reaction monitoring (MRM) mode after the GC separation on an HP-5MS column (30 m ×0. 25 mm ×0. 25μm). The eight point calibration curves showed a good linearity for all the congeners (0. 997 3 - 0. 997 6 ). The limits of detection ( LODs) ranged from 0. 1 to 0. 5 μg/kg. The relative standard deviations ( RSDs) were not more than 14. 3% and the spiked recoveries were in the range of 72. 9% - 106. 2%. The developed analytical method is rapid and accurate, and suitable for the determination of PAEs in soil.关键词
气相色谱/串联质谱/邻苯二甲酸酯/增塑剂/土壤Key words
gas chromatography (GC)/ tandem mass spectrometry (MS/MS)/ phthalic acid esters (PAEs)/ plasticizer/ soil分类
化学化工引用本文复制引用
李红,田福林,任雪冬,王歆睿..气相色谱-串联质谱法测定土壤中的邻苯二甲酸酯[J].色谱,2011,29(6):563-566,4.基金项目
辽宁省博士科研启动基金项目(No.20101051). （No.20101051）
