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花生壳制备微孔炭及其在电化学超级电容器中的应用

郭培志 季倩倩 张丽莉 赵善玉 赵修松

物理化学学报2011,Vol.27Issue(12):2836-2840,5.
物理化学学报2011,Vol.27Issue(12):2836-2840,5.DOI:10.3866/PKU.WHXB20112836

花生壳制备微孔炭及其在电化学超级电容器中的应用

Preparation and Characterization of Peanut Shell-Based Microporous Carbons as Electrode Materials for Supercapacitors

郭培志 1季倩倩 1张丽莉 2赵善玉 2赵修松1

作者信息

  • 1. 青岛大学化学化工与环境学院, 纤维新材料与现代纺织国家重点实验室培育基地, 山东青岛266071
  • 2. Department ofChemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117576
  • 折叠

摘要

Abstract

Microporous carbons (PSC-1 and PSC-2) were obtained directly by the carbonization of peanut shells without and with NaOH solution pretreatment, respectively. Both samples have a main pore voltammograms (CVs) of the PSC-1 and PSC-2 electrodes and the symmetrical supercapacitors show almost rectangular shape indicating excellent capacitance features. The specific capacitances of PSC-1 system using porous carbon as the working electrode, a platinum electrode as the counter electrode and a Ag/AgCl electrode as the reference electrode. Furthermore, the electrodes in both three-electrode systems and supercapacitors show high stability and capacitance retainability after 1000 cycles. The formation mechanisms for the two microporous carbons and the relationship between the carbon materials and their electrochemical properties are discussed based on the experimental results.

关键词

超级电容器/电极/微孔炭/花生壳/电容

Key words

Supercapacitor/Electrode/Microporous carbon/Peanut shell/Capacitance

分类

化学化工

引用本文复制引用

郭培志,季倩倩,张丽莉,赵善玉,赵修松..花生壳制备微孔炭及其在电化学超级电容器中的应用[J].物理化学学报,2011,27(12):2836-2840,5.

基金项目

国家自然科学基金(20803037,21143006),青岛市应用基础研究项目(11-2-4-2-(8)-jch)和"泰山学者"计划资助 (20803037,21143006)

物理化学学报

OA北大核心CSCDCSTPCDSCI

1000-6818

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