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HAP自组装球的简易合成及其光催化增效作用

杨小红 刘畅 刘金库 朱子春

物理化学学报2011,Vol.27Issue(12):2939-2945,7.
物理化学学报2011,Vol.27Issue(12):2939-2945,7.DOI:10.3866/PKU.WHXB20112939

HAP自组装球的简易合成及其光催化增效作用

Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties

杨小红 1刘畅 2刘金库 2朱子春1

作者信息

  • 1. 池州学院化学系,安徽池州247000
  • 2. 华东理工大学化学系,上海200237
  • 折叠

摘要

Abstract

Hydroxyapatite (HAP) nanoribbon spheres with well-defined nanoscale structures and regular morphology were successfully synthesized using a bioactive cooperate template. The spheres are about 5-6 μm in diameter and they form from nanoribbons of 2.5 to 3 |jm in length. The morphologies, structures, and surface areas of the products were studied by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and Brunauer-Emmett-Teller (BET) analysis. In addition, the products were used as carried materials for the synthesis of the HAP/ZnO composite catalyst. The degradation rate of rhodamine B (RhB) increased by 125% and the recovery increased by 23.1% when using the composite as a catalyst compared with the ZnO nanoparticles. Possible mechanisms for the formation of the HAP assembly microspheres and their synergistic action are also discussed.

关键词

羟基磷灰石/氧化锌/纳米组装球/光催化/增效作用

Key words

HAP/ ZnO/ Assembly sphere/ Photocatalysis/ Synergized action

分类

化学化工

引用本文复制引用

杨小红,刘畅,刘金库,朱子春..HAP自组装球的简易合成及其光催化增效作用[J].物理化学学报,2011,27(12):2939-2945,7.

基金项目

国家自然科学基金(21071024)、安徽省科技计划项目(10140702017)、安徽省教育厅重点科研项目(KJ2010A244)和污染控制与资源化研究国家重点实验室开放课题(PCRRF09005)资助 (21071024)

物理化学学报

OA北大核心CSCDCSTPCDSCI

1000-6818

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