物理化学学报2011,Vol.27Issue(12):2939-2945,7.DOI:10.3866/PKU.WHXB20112939
HAP自组装球的简易合成及其光催化增效作用
Facile Synthesis of Assembly HAP Nanoribbon Spheres and the Synergized Action of Its Photocatalytic Properties
摘要
Abstract
Hydroxyapatite (HAP) nanoribbon spheres with well-defined nanoscale structures and regular morphology were successfully synthesized using a bioactive cooperate template. The spheres are about 5-6 μm in diameter and they form from nanoribbons of 2.5 to 3 |jm in length. The morphologies, structures, and surface areas of the products were studied by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and Brunauer-Emmett-Teller (BET) analysis. In addition, the products were used as carried materials for the synthesis of the HAP/ZnO composite catalyst. The degradation rate of rhodamine B (RhB) increased by 125% and the recovery increased by 23.1% when using the composite as a catalyst compared with the ZnO nanoparticles. Possible mechanisms for the formation of the HAP assembly microspheres and their synergistic action are also discussed.关键词
羟基磷灰石/氧化锌/纳米组装球/光催化/增效作用Key words
HAP/ ZnO/ Assembly sphere/ Photocatalysis/ Synergized action分类
化学化工引用本文复制引用
杨小红,刘畅,刘金库,朱子春..HAP自组装球的简易合成及其光催化增效作用[J].物理化学学报,2011,27(12):2939-2945,7.基金项目
国家自然科学基金(21071024)、安徽省科技计划项目(10140702017)、安徽省教育厅重点科研项目(KJ2010A244)和污染控制与资源化研究国家重点实验室开放课题(PCRRF09005)资助 (21071024)