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239Pu在泥岩和砂岩上的吸附分配系数

于静 王旭辉 金玉仁 黄能斌 司高华 贾海红 刘东旭

核化学与放射化学2011,Vol.33Issue(3):173-178,6.
核化学与放射化学2011,Vol.33Issue(3):173-178,6.

239Pu在泥岩和砂岩上的吸附分配系数

Distribution Coefficient of Plutonium on Sandstone and Mudstone

于静 1王旭辉 1金玉仁 1黄能斌 1司高华 1贾海红 1刘东旭1

作者信息

  • 1. 西北核技术研究所,陕西西安,710024
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摘要

Abstract

The sorption distribution coefficients Kd of plutonium on mudstone and sandstone are studied by batch experiments. The experimental factors influencing Kd are stone granu-larity, the pH value of the aqueous phase, the solid-to-liquid ratio, different ions existing in aqueous phase. It is shown Kd of Pu on mudstone is about 120 mL/g, Kd of Pu on sandstone is 1. 60×104 mL/g. The sandstone has greater sorption ability of Pu than mudstone. It is indicated that the Kd of Pu is increasing while granularity of rock minimizing, pH and ratio of solid and liquid increasing; the sorption of Pu on rocks is strongly in aqueous nitrate solu-tion than simulated groundwater.

关键词

239Pu;静态法;分配系数

Key words

239Pu/ batch experiments/ distribution coefficient

分类

能源科技

引用本文复制引用

于静,王旭辉,金玉仁,黄能斌,司高华,贾海红,刘东旭..239Pu在泥岩和砂岩上的吸附分配系数[J].核化学与放射化学,2011,33(3):173-178,6.

核化学与放射化学

OA北大核心CSCDCSTPCD

0253-9950

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