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苯丙自交联改性无皂乳液表面施胶剂的合成

张恒 赵娜娜 刘丽丽

中国造纸Issue(7):25-28,4.
中国造纸Issue(7):25-28,4.

苯丙自交联改性无皂乳液表面施胶剂的合成

Synthesis of Modified Self-crosslinking Styrene-acrylic Soap-free Emulsion as Surface Sizing agent

张恒 1赵娜娜 2刘丽丽1

作者信息

  • 1. 青岛科技大学化工学院,山东青岛,266042
  • 2. 南京林业大学江苏省制浆造纸科学与技术重点实验室,江苏南京,210037
  • 折叠

摘要

Abstract

The synthesis of styrene-acrylic emulsion by soap-free emulsion polymerization was researched in this paper. Functional monomers, such as diacetone acrylamide (DAAM) ,acrylamide( AM) ,and reactive emulsifier formulated by non-ionic reactive surfactant KL-100 and anionic reactive emulsifier COFS-1, were added in the emulsion system. The optimum conditions for emulsion polymerization were obtained : the ratio of hard and soft monomers is 1, reaction temperature 75 - 80℃, emulsifier dosage 4wt % , and functional monomers dosage 2wt%. Both water resistance and gloss of the paper surface sized by the emulsion were very high.

关键词

苯丙乳液/无皂乳液聚合/表面施胶剂/自交联/反应型乳化剂

Key words

styrene-acrylic soap-free emulsion/surface sizing agent/functional monomers/reactive emulsifier

分类

轻工纺织

引用本文复制引用

张恒,赵娜娜,刘丽丽..苯丙自交联改性无皂乳液表面施胶剂的合成[J].中国造纸,2011,(7):25-28,4.

基金项目

江苏省制浆造纸科学与技术重点实验室开放基金项目(200905). (200905)

中国造纸

OA北大核心CSTPCD

0254-508X

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