中国造纸Issue(7):25-28,4.
苯丙自交联改性无皂乳液表面施胶剂的合成
Synthesis of Modified Self-crosslinking Styrene-acrylic Soap-free Emulsion as Surface Sizing agent
摘要
Abstract
The synthesis of styrene-acrylic emulsion by soap-free emulsion polymerization was researched in this paper. Functional monomers, such as diacetone acrylamide (DAAM) ,acrylamide( AM) ,and reactive emulsifier formulated by non-ionic reactive surfactant KL-100 and anionic reactive emulsifier COFS-1, were added in the emulsion system. The optimum conditions for emulsion polymerization were obtained : the ratio of hard and soft monomers is 1, reaction temperature 75 - 80℃, emulsifier dosage 4wt % , and functional monomers dosage 2wt%. Both water resistance and gloss of the paper surface sized by the emulsion were very high.关键词
苯丙乳液/无皂乳液聚合/表面施胶剂/自交联/反应型乳化剂Key words
styrene-acrylic soap-free emulsion/surface sizing agent/functional monomers/reactive emulsifier分类
轻工纺织引用本文复制引用
张恒,赵娜娜,刘丽丽..苯丙自交联改性无皂乳液表面施胶剂的合成[J].中国造纸,2011,(7):25-28,4.基金项目
江苏省制浆造纸科学与技术重点实验室开放基金项目(200905). (200905)