西北师范大学学报（自然科学版）2011，Vol.47Issue(4)：56-60,68,6.
辉光放电等离子体引发制备聚丙烯酸/蛭石合高吸水树脂及其性能研究
Synthesis and characterization of acrylic acid/vermiculite superabsorbent resin via glow-discharge electrolysis plasma
摘要
Abstract
Crosslinking graft polymerization of poly (acrylic acid)/vermiculite superabsorbent resin in aqueous solution is prepared by using glow-discharge electrolysis plasma, in which acrylic acid and vermiculite are used as starting material, N,N -methylenebisacrylamide as a crosslinking agent. To optimize the synthesis conditions, seven important parameters of the graft polymerization are examined in detail, such as the discharge voltage, discharge time, neutralization of acrylic acid, polymerization temperature, amounts of crosslinking agent, vermiculite and acrylic acid used. The structure, thermal stability and morphology of resulting product are characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis(TGA), scanning electron microscopy(SEM) , respectively. Under the optimal condition, the behavior of the obtained poly (acrylic acid)/vermiculite superabsorbent is tested with a satisfactory result, that is, the absorption for distilled water is 1 333 g·g-1, for 0.15 mol·L-1 sodium chloride solution 73 g·g-1.关键词
辉光放电等离子体/蛭石/丙烯酸/复合吸水树脂Key words
glow-discharge electrolysis plasma (GDEP )/vermiculite ( VMT)/ acrylic acid(AA)/ superabsorbent resin分类
化学化工引用本文复制引用
高锦章,马得莉,俞洁,杨武,李兴发,李岩..辉光放电等离子体引发制备聚丙烯酸/蛭石合高吸水树脂及其性能研究[J].西北师范大学学报（自然科学版）,2011,47(4):56-60,68,6.基金项目
教育部重点科技基金资助项目(00250) （00250）
甘肃省自然科学基金资助项目(3ZS041-A25-028,096RJ2A120) （3ZS041-A25-028,096RJ2A120）
西北师范大学科技创新工程资助项目(NWNU-KJCXGC-01) （NWNU-KJCXGC-01）
