硅酸盐学报2011，Vol.39Issue(7)：1090-1096,7.
基于锐钛矿相二氧化钛溶胶的高效染料敏化太阳能电池
High Efficiency Dye-Sensitized Solar Cells Based on the Anatase TiO2 Sols
摘要
Abstract
TiO2 precipitates were treated with dilute HNO3 solution or H2O2 solution, anatase TiO2 sols and peroxotitanium acid (PTA) solution were obtained, respectively. Both anatase TiO2 sols and PTA solution were subjected to further hydrothermal treatment, and TiO2 nanorod sols with a specific surface area of more than 100m2/g were formed via the oriented attachment mechanism. The anatase nanorods were used to fabricate dye-sensitized solar cells (DSSCs), and cells with a higher open-circuit voltage were observed. The anatase nanorod sols were also used to make compact layers over FTO conductive glass, and infiltrated into porous TiO2 layers using Degussa P25 titania as raw material by doctor-blade technique to elimination large pores and defects in DSSCs anodes. The sols treated anodes were sintered and assembled into DSSCs, and the photoelectric conversion efficiency of resulted DSSCs increased from 4.15% to 5.63% under AM1.5 simulated solar irradiation.关键词
溶胶/锐钛矿相二氧化钛纳米棒/染料敏化太阳能电池/阻挡层/内渗透Key words
sol/ anatase titanium dioxide nanorods/ dye-sensitized solar cells/ compact layer/ infiltration分类
化学化工引用本文复制引用
郝艳明,石国英,钱迪峰,张青红..基于锐钛矿相二氧化钛溶胶的高效染料敏化太阳能电池[J].硅酸盐学报,2011,39(7):1090-1096,7.基金项目
国家自然科学基金(No.50772127)、上海市重点学科建设项目(B603)资助. （No.50772127）
