化工进展2011，Vol.30Issue(7)：1478-1481,1590,5.
活性碳纤维低温选择性催化还原NO的机理研究进展
Research advance in mechanism of low-temperature SCR of NO on carbon materials
黄华存1
作者信息
- 1. 河池学院化学与生命科学系，广西宜州546300
- 折叠
摘要
Abstract
The behavior of the reactant molecules on carbon materials surface, formation of adsorbed NO2 , dimer (NO)2, -NO2 or pyridine compounds from single component NO is reviewed. When NO and O2 coexists. NO is oxidized to NO2 by the adsorbed O2. When NO, O2 and NH3 coexists, the reaction occurs between adsorbed NH3 and adsorbed NO2. The mechanism of selective catalytic reduction (SCR) of NO on activated carbon fibers (ACF) catalyst is presented as follows. At a low temperature NH3-SCR follows the Langmuir-Hinshelwood mechanism. While at a high temperature NH3-SCR follows the Eley-Rideal mechanism. The catalyst pore structure characteristics and surface chemical functional groups are the main factors of the low temperature SCR of NO.关键词
碳材料；活性碳纤维；反应机理；选择性催化还原Key words
carbon material/ activated carbon fiber/ reaction mechanism/ selective catalytic reduction分类
化学化工引用本文复制引用
黄华存..活性碳纤维低温选择性催化还原NO的机理研究进展[J].化工进展,2011,30(7):1478-1481,1590,5.
