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微波辐射条件下丙烯海松酸的合成

王宏晓 商士斌 徐徐 谭卫红

化工进展2011,Vol.30Issue(7):1602-1606,5.
化工进展2011,Vol.30Issue(7):1602-1606,5.

微波辐射条件下丙烯海松酸的合成

Synthesis of acrylpimaric acid under microwave irradiation

王宏晓 1商士斌 2徐徐 1谭卫红2

作者信息

  • 1. 中国林业科学研究院林产化学工业研究所,国家林业局林产化学工程重点开放性实验室,江苏南京210042
  • 2. 中国林业科学研究院林业新技术研究所,北京100091
  • 折叠

摘要

Abstract

Acrylpimaric acid was synthesized under microwave irradiation by using rosin and acrylic acid as raw materials. The effects of reaction time, microwave power, temperature, and mole ratio of acrylic acid to resin acids on the Diels-Alder addition were investigated. The optimum synthesis conditions were obtained as follows: reaction time 60 min, reaction temperature 180 ℃, microwave power 110 W, acrylic acid /resin acids ratio 1.2 : 1 (mole ratio) . The results showed that microwave could accelerate the reaction rate significantly.

关键词

松香;丙烯海松酸;Diels-Alder加成反应;微波辐射

Key words

rosin/ acrylpimaric/ Diels-Alder addition/ microwave irradiation

分类

化学化工

引用本文复制引用

王宏晓,商士斌,徐徐,谭卫红..微波辐射条件下丙烯海松酸的合成[J].化工进展,2011,30(7):1602-1606,5.

基金项目

国家自然科学基金项目(31070519)。 (31070519)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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