化工进展2011,Vol.30Issue(7):1602-1606,5.
微波辐射条件下丙烯海松酸的合成
Synthesis of acrylpimaric acid under microwave irradiation
摘要
Abstract
Acrylpimaric acid was synthesized under microwave irradiation by using rosin and acrylic acid as raw materials. The effects of reaction time, microwave power, temperature, and mole ratio of acrylic acid to resin acids on the Diels-Alder addition were investigated. The optimum synthesis conditions were obtained as follows: reaction time 60 min, reaction temperature 180 ℃, microwave power 110 W, acrylic acid /resin acids ratio 1.2 : 1 (mole ratio) . The results showed that microwave could accelerate the reaction rate significantly.关键词
松香;丙烯海松酸;Diels-Alder加成反应;微波辐射Key words
rosin/ acrylpimaric/ Diels-Alder addition/ microwave irradiation分类
化学化工引用本文复制引用
王宏晓,商士斌,徐徐,谭卫红..微波辐射条件下丙烯海松酸的合成[J].化工进展,2011,30(7):1602-1606,5.基金项目
国家自然科学基金项目(31070519)。 (31070519)