高等学校化学学报2011,Vol.32Issue(7):1634-1638,5.
聚苯乙烯光子晶体薄膜的光化学行为
Photochemical Behavior of Polystyrene Photonic Crystals Film
摘要
Abstract
The morphology, optical properties and wettability of polystyrene (PS) photonic crystals (PC) films were studied under UV irradiation. The hydrophilic carbonyl group formed on the surface of PS microsphere after UV irradiation, which was demonstrated by characterizing the chemical composition of the surface using FTIR. Scanning electron microscopic images show that the PS sphere would contract, deform and melt compa-nying with longer time of UV irradiation. The in situ reflectance and transmittance spectra indicated that the PC film could preserve good optical properties and changed from hydrophobic to hydrophilic in 20 min of UV irradiation. Therefore, the hydrophilic polymer PC film with good optical properties can be obtained by controlling the UV irradiation time, which will be of great importance for the application of PC in the special system.关键词
聚苯乙烯/光子晶体/紫外光照/光化学交联/浸润性Key words
Polystyrene/Photonic crystal/UV irradiation/Photochemical cross-linking/Wettability分类
化学化工引用本文复制引用
张玉琦,郝欣,魏清渤,杨华,王俏,宋延卫..聚苯乙烯光子晶体薄膜的光化学行为[J].高等学校化学学报,2011,32(7):1634-1638,5.基金项目
陕西省教育厅专项研究计划(批准号:11JK0587)资助. (批准号:11JK0587)