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碱处理棉纤维结构及其在LiCi/DMAc中的溶解特性

郭静 黄文飞 王金香 徐磊

大连工业大学学报2011,Vol.30Issue(4):270-273,4.
大连工业大学学报2011,Vol.30Issue(4):270-273,4.

碱处理棉纤维结构及其在LiCi/DMAc中的溶解特性

Structure and dissolution characteristics in LiCl/DMAc of cotton cellulose after pretreated with NaOH solution

郭静 1黄文飞 1王金香 2徐磊1

作者信息

  • 1. 大连工业大学化工与材料学院,辽宁大连116034
  • 2. 江苏华亚化纤有限公司,江苏宜兴 214253
  • 折叠

摘要

Abstract

Cellulose was pretreated with NaOH solution. Crystal structure changes of cellulose pretreated with different conditions were investigated, and the change of crystallinity and crystal size was characterized by X ray diffraction. The solubility and stability of solution of cotton cellulose after pretreated with NaOH solution. The results indicate that after pretreated, crystal structure of cellulose changed very obviously, X ray diffraction peaks of cellulose decreased very obviously, crystallinity and crystal size also changed, and changed very obviously with NaOH concentration, but the pretreatment temperature and time have little effect on the changes. Pretreated cellulose can dissolve in LiCl/DMAc, and can dissolve completely in LiCl/DMAc solution with 10% of LiCl concentration. Cotton cellulose/LiCl/DMAc solution begin to phase separation after 48 h, then formed gel, and separate out solvent.

关键词

棉纤维/碱处理/LiCl/DMAc/溶解特性

Key words

cotton cellulose/alkali treatment/LiCl/DMAc/dissolution

分类

轻工纺织

引用本文复制引用

郭静,黄文飞,王金香,徐磊..碱处理棉纤维结构及其在LiCi/DMAc中的溶解特性[J].大连工业大学学报,2011,30(4):270-273,4.

基金项目

辽宁省教育厅重点实验室项目(LS2010010). (LS2010010)

大连工业大学学报

OA北大核心CSTPCD

1674-1404

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