高等学校化学学报2011，Vol.32Issue(8)：1714-1719,6.
芹菜素的电喷雾萃取电离串联质谱
Extrative Electrospray Ionization Tandem Mass Spectrometry of Apigenin
摘要
Abstract
The extractive electrospray ionization tandem mass spectrometry (EESI-MS") of apigenin was studied using both positive and negative ion modes. The results showed that the detection of apigenin was more sensitive in negative ion mode than that in positive ion mode. By comparing EESI-MS spectra with electrospray ionization mass spectrometry( ESI-MS) spectra of apigenin, we found that EESI mode is softer than ESI mode. The mechanism of the fragmentation of apigenin was also discussed in detail based on the experimental collision-induced dissociation(CID) data recorded in these experiments, and was confirmed by the ESI-MS. The study is useful for the rapid and direct determination of trace amount of apigenin in complex matrix by EESI-MS.关键词
芹菜素/串联质谱/电喷雾萃取电离质谱/电喷雾电离质谱/裂解规律Key words
Apigenin/ Tandem mass spectrometry/ Extraction electrospray ionization mass spectrometry/Electrospray ionization mass spectrometry/ Fragmentation mechanism分类
化学化工引用本文复制引用
丁健桦,王兴祥,张慧,潘素素,罗明标,李建强,陈焕文..芹菜素的电喷雾萃取电离串联质谱[J].高等学校化学学报,2011,32(8):1714-1719,6.基金项目
科技部国际科技合作项目(批准号:2009DFA41880)和中国科学院知识创新工程重大项目(批准号:KSCX1-YW-09-08)资助. （批准号:2009DFA41880）
