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共混法制备硅酸镁锂/PAAS/KOH/H2O凝胶电解质

颜攀敦 桑商斌 邓明周 伍秋美

电池2011,Vol.41Issue(4):206-209,4.
电池2011,Vol.41Issue(4):206-209,4.

共混法制备硅酸镁锂/PAAS/KOH/H2O凝胶电解质

Preparing magnesium lithium silicate/PAAS/KOH/H2O gel electrolyte by blending method

颜攀敦 1桑商斌 1邓明周 1伍秋美2

作者信息

  • 1. 中南大学化学化工学院,湖南长沙410083
  • 2. 中南大学粉末冶金研究院,湖南长沙410083
  • 折叠

摘要

Abstract

The composite inorganic alkaline gel electrolyte of magnesium lithium silicate( MLS)/sodium polyacrylate (PAAS)/ KOH/H2O was prepared from MLS, PAAS and KOH by blending method. The samples were studied by AC impedance, cyclic voltammetry and galvanostatic charge-discharge test.At room temperature, the conductivity of prepared gel electrolyte was the same order as that of the 6 mol/L KOH solution,its electrochemical stable window was about 1.6 V. The charge-discharge efficiency of the MH/Ni battery assembled with MLS/PAAS/KOH/H2O gel dectrolyte [ m(MLS): ro(PAAS): m(KOH): m(H2O) =0.6:1.0: 5.0:15.0] was still above 95% after 250 cycles(galvanostatic charged-discharged with 1.0 C).

关键词

复合无机碱性凝胶电解质/共混法/电导率/MH/Ni电池

Key words

composite inorganic alkaline gel electrolyte/ blending method/ conductivity/ MH/Ni battery

分类

信息技术与安全科学

引用本文复制引用

颜攀敦,桑商斌,邓明周,伍秋美..共混法制备硅酸镁锂/PAAS/KOH/H2O凝胶电解质[J].电池,2011,41(4):206-209,4.

基金项目

广东省教育部科技部企业科技特派员行动计划专项项目(2009B090600087) (2009B090600087)

电池

OA北大核心CSCDCSTPCD

1001-1579

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