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NC/GAP-TPE共混聚合物的制备和性能研究

左海丽 肖乐勤 菅晓霞 周伟良

固体火箭技术2011,Vol.34Issue(4):488-491,4.
固体火箭技术2011,Vol.34Issue(4):488-491,4.

NC/GAP-TPE共混聚合物的制备和性能研究

Preparation and characterization of polymer blends of NC and GAP-TPE

左海丽 1肖乐勤 1菅晓霞 1周伟良1

作者信息

  • 1. 南京理工大学化工学院,南京210094
  • 折叠

摘要

Abstract

A series of blends of energetic thermoplastic polyurethane( GAP-TPE)and Nitrocellulose( NC) were prepared by the way of chain extension,blend and aging. The structures of the blends were analyzed by means of FT1R spectroscopy, wide-angle Xray diffraction,and scanning electron microscopy. The compatibility and properties of the blends were characterized by dynamic mechanical analysis( DMA)and tensile testing. It suggests that nitrocellulose molecules penetrate into the polyurethane and interrupt the intra-hydrogen bonding between the hard and soft segments. The results indicate that the blended sheets exhibited good miscibility. The tensile strength increased with an increase of NC content. The blends NC/GAP-TPE having 5%~20% NC exhibited a significant increase from 10.4 Mpa to 20.4 Mpa for tensile strength ,49% increased.

关键词

GAP/热塑性弹性体/硝化棉/共混

Key words

glycidyl azide polymer/energetic thermoplastic elastomer/nitrocellulose/blend

分类

航空航天

引用本文复制引用

左海丽,肖乐勤,菅晓霞,周伟良..NC/GAP-TPE共混聚合物的制备和性能研究[J].固体火箭技术,2011,34(4):488-491,4.

固体火箭技术

OA北大核心CSCDCSTPCD

1006-2793

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