化工学报2011，Vol.62Issue(9)：2651-2656,6.DOI:10.3969/j.issn.0438-1157.2011.09.039
潜伏性2MMZ-PS微胶囊固化剂的制备与表征
Preparation and characterization of 2MMZ-PS microcapsule-type latent curing agent
摘要
Abstract
A novel heat released microcapsule-type latent curing agent was prepared by solvent evaporation technique with 2-methylimidazole (2MMZ) as core material and polystyrene (PS) as wall material. The chemical structure, core material content, surface morphology, size distribution and curing characteristics of this microcapsule-type curing agent were characterized by FT-IR, TGA, SEM, granulometer and DSC. The obtained microcapsules had a smooth surface and displayed a narrow size distribution with the mean size about 10.18 f*m, and its core material content was about 40. 36%. In addition, the one-component adhesive made from the microcapsules and epoxy resin E-51 showed excellent curing characteristics and latent properties. It was found that the E-51/2MMZ-PS microcapsule system could be cured at 100 °C in 1 h and its shelf life at room temperature was more than 1 month.关键词
微胶囊/潜伏性固化剂/环氧树脂/溶剂挥发法Key words
microcapsule/ latent curing agent/ epoxy resin/ solvent volatilization method分类
化学化工引用本文复制引用
史有强,张秋禹,尹雅楠,尹常杰,张宝亮,顾军渭..潜伏性2MMZ-PS微胶囊固化剂的制备与表征[J].化工学报,2011,62(9):2651-2656,6.基金项目
国家自然科学基金项目(50773063) （50773063）
国家重点基础研究发展计划项目(2010CB635111) （2010CB635111）
西北工业大学基础研究基金项目(G9KY1020) （G9KY1020）
西北工业大学研究生创业种子基金项目(Z2010076). （Z2010076）
