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从复合固体推进剂中浸取高氯酸铵的动力学过程

王军 蔺向阳 潘仁明

火炸药学报Issue(4):70-74,5.
火炸药学报Issue(4):70-74,5.

从复合固体推进剂中浸取高氯酸铵的动力学过程

Dynamic Process of Ammonium Perchlorate Leached from Composite Solid Propellant

王军 1蔺向阳 1潘仁明1

作者信息

  • 1. 南京理工大学化工学院,江苏南京210094
  • 折叠

摘要

Abstract

In order to investigate the dynamic process of ammonium perchlorate(AP) leaching from composite solid propellant by using water as solvent,the extraction process of AP with water was analyzed. Equilibrium separation factor and recovery ratio of AP were compared at different temperatures and specimen s thickness. The internal structure of the dissolved propellants was observed by SEM. The results show that as temperature decreases and specimen's thickness increases,leaching-rate coefficient increases. Leaching-rate is a constant under certain temperature and specimen's thickness. Leaching-rate equation is consistent with first order dynamic equation. Leaching AP from composite solid propellants is an internal diffusion process that controlled by diffusion of water and ammonium perchlorate in the propellants.

关键词

物理化学/复合固体推进剂/高氯酸铵/浸取/动力学

Key words

physical chemistry/ composite solid propellant/ ammonium perchlorate extraction/ dynamics

分类

军事科技

引用本文复制引用

王军,蔺向阳,潘仁明..从复合固体推进剂中浸取高氯酸铵的动力学过程[J].火炸药学报,2011,(4):70-74,5.

火炸药学报

OA北大核心CSCDCSTPCD

1007-7812

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