人工晶体学报2011，Vol.40Issue(4)：932-937,6.
非水解和水解溶胶-凝胶法制备TiO2薄膜的对比研究
Comparative Research on the Preparation of TiO2 Films by Non-hydrolytic and Hydrolytic Sol-gel Method
摘要
Abstract
TiO2 film was prepared by non-hydrolytic and hydrolytic sol-gel method, respectively. The sol-gel process, the phase transformation and the reaction mechanism of TiO2 film were studied by FTIR, TG-DSC and XRD analysis. The results show that the reaction mechanism of the preparation of TiO2 film by non-hydrolytic and hydrolytic sol-gel method is different. During the hydrolytic sol-gel process, the Ti-ORbond in the tetrabutyl titanate cleavages into Ti-OH bond, which react with Ti-OH or Ti-OR to form Ti-O-Ti. The non-hydrolytic route involves the Ti-Cl react with Ti-OR by a nuclear reaction to form Ti-O-Ti bond, on the condition of not forming Ti-OH bond. The phase transition temperature of anatase-to-rutile by non-hydrolytic sol-gel is 750 ℃, which is higher than that by hydrolytic sol-gel methods.关键词
非水解溶胶-凝胶法/水解溶胶-凝胶法/TiO2薄膜Key words
non-hydrolytic sol-gel/hydrolytic sol-gel/TiO2 film分类
数理科学引用本文复制引用
包镇红,江伟辉,苗立锋,朱庆霞..非水解和水解溶胶-凝胶法制备TiO2薄膜的对比研究[J].人工晶体学报,2011,40(4):932-937,6.基金项目
国家自然科学基金(50762005,50962006) （50762005,50962006）
江西省青年自然科学基金(2009GQC0074)资助项目 （2009GQC0074）
