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天然沸石对氨氮的吸附特性研究

邹娟 郭雪松 李琳 刘俊新

山西大学学报(自然科学版)2011,Vol.34Issue(3):485-491,7.
山西大学学报(自然科学版)2011,Vol.34Issue(3):485-491,7.

天然沸石对氨氮的吸附特性研究

Characteristics of Ammonium Adsorption on Natural Zeolite

邹娟 1郭雪松 1李琳 1刘俊新1

作者信息

  • 1. 中国科学院生态环境研究中心,北京100085
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摘要

Abstract

Adsorption kinetics,adsorption equilibrium isotherms and the effect of pH on the removal of ammonium using natural zeolite were investigated. The results showed that the adsorption plots fit to Lang-muir and Freundlich models very well, with the maximum ammonium adsorption capacity of 8. 10 mg/g. Compared with the intra-particle diffusion kinetic model, the pseudo-second-order model reflected more reasonable for ammonium ion uptake on zeolite. The optimum adsorption capacity of ammonium was obtained at pH in the range of 4. 0~8. 0. And a vertical flow constructed wetland ( VFCW) was constructed with the zeolite. The results showed that the ammonium removal efficiency of VFCW (R, %) was more than 90% in the first 3 months of operation,and decreased gradually in the subsequent 7 months. When the rate of the cumulative amount of ammonium in the influent to the maximum ammonium adsorption capacity of the zeolite filled in VFCW (r,%) was less than 150%, there was a linear relationship between R and r, which will be benefit for the design and operation of VFCW in the actual application.

关键词

污水处理/氨氮去除/沸石/吸附/垂直流人工湿地

Key words

wastewater treatment/ammonium removal/zeolite/adsorption/vertical flow constructed wetland

分类

资源环境

引用本文复制引用

邹娟,郭雪松,李琳,刘俊新..天然沸石对氨氮的吸附特性研究[J].山西大学学报(自然科学版),2011,34(3):485-491,7.

基金项目

国家科技重大专项“水污染控制与治理”资助(编号2008ZX07101-006-03) (编号2008ZX07101-006-03)

山西大学学报(自然科学版)

OA北大核心CSCDCSTPCD

0253-2395

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