西安工程大学学报2011,Vol.25Issue(3):357-361,5.
二苯乙二酮苯甲酰腙的合成、晶体结构及荧光性
Synthesis of 1,2-diphenyl ethanedionc benzohydrazide and its crystal structure and fluorescence properties
摘要
Abstract
The 1,2-diphenyl ethanedionc benzohydrazide was synthesized by the reaction of 1,2-diphenyl ethanedionc and benzohydrazide. The crystal structure of the compound was characterized by X-ray diffraction and Fluorescence. It was assigned to triclinic crystal system, space group P-l, cell data: α = 0.561 0(4) run, a = 99.868(9)°,6 = 1.028 5(8)nm,0 = 98. 775(8)°,c = 1.565 l(12)nm,y = 103.503(8)°, V = 0.847 5( 11) nm3, Z = 2,μ=0.087mm-1,Dc = 1. 350mg/m3, F(000) =364, R1=0.146 l[I>2sigma(I) ] ,wR2 =0.412 3(all data). Fluorescence spectra showed that the compound is a strong fluorescent substances,and can be used as a potential photoactive materials.关键词
酰腙/晶体结构/X射线衍射/配体/荧光Key words
thydrazone/ crystal structure /X-Ray diffraction/ligand/ fluorescence分类
化学化工引用本文复制引用
杨滋渊,王亮,刘娟,郑长征..二苯乙二酮苯甲酰腙的合成、晶体结构及荧光性[J].西安工程大学学报,2011,25(3):357-361,5.基金项目
陕西省自然科学基金项目(2009JM2012) (2009JM2012)