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沉淀法处理含铜废水及其沉淀产物的表征

李新颖 Francis Ruzagiliza Innocent 陈泉源 薛罡

化工环保2011,Vol.31Issue(4):298-303,6.
化工环保2011,Vol.31Issue(4):298-303,6.

沉淀法处理含铜废水及其沉淀产物的表征

Treatment of Copper-Containing Wastewater by Precipitation and Characterization of Precipitate

李新颖 1Francis Ruzagiliza Innocent 1陈泉源 1薛罡1

作者信息

  • 1. 东华大学环境科学与工程学院,上海201620
  • 折叠

摘要

Abstract

The simulated acidic copper-containing wastewater was treated using Ca(OH)2, Na2CO3 and Na2S as precipitants. The experimental results show that; The order of copper ion removal rates is Ca(OH)2 >Na2CO3 >Na2S; After precipitation for 60 min, the order of sludge sedimentation volumes is Na2CO3 > Ca(OH)2 > Na2S; The order of the supernatant turbidities is Ca(OH)2 > Na2CO3> Na2S. With the increasing of the solution pH, the absolute value of £ potential of the supernatant decreases for Ca(OH)2 precipitant, but increases for Na2CO3 and Na2S precipitants. When Ca(OH)2 is used as precipitant, the main precipitates are CaSO4 ·2H2O and CuO; When Na2CO3 is used as precipitant, the main precipitate is Cu4(SO4) (OH)6·2H2O; When Na2S is used as precipitant, the main precipitates are CuS and CuSO4 · 5H2O. The advantage of using Ca(OH)2 as precipitant is evident.

关键词

含铜废水/沉淀法/沉淀剂/ξ电位/浊度/污泥

Key words

copper-containing wastewater/ precipitation method/ precipitant/ & potential/ turbidity/ sludge

分类

化学化工

引用本文复制引用

李新颖,Francis Ruzagiliza Innocent,陈泉源,薛罡..沉淀法处理含铜废水及其沉淀产物的表征[J].化工环保,2011,31(4):298-303,6.

基金项目

上海市重点学科建设项目基金资助项目(B604). (B604)

化工环保

OA北大核心CSCDCSTPCD

1006-1878

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