高等学校化学学报2011，Vol.32Issue(9)：2175-2180,6.
Mn4-硫杂杯[4]芳烃单元的溶剂导向超分子组装
Solvent-directing Supramolecular Assemblies of Mn4 -thiacalix [4]arene
摘要
Abstract
Two tetranuclear compounds,Mn4 ( T4A ) 2 ( 1 ) and Mn4 ( T4A ) 2 ( DMF ) 2 ( 2 ) ( T4A =thiacalix [4]arene),were synthesized via the solvothermal reaction of manganese ( Ⅱ ) acetate and thiacalix [4]arene with different solvents.Single-crystal analysis reveals that compound 1 with a two-dimensional Kagomé lattice was obtained in the mixed CHCl3/CH3OH solvent,while the interpenetrated 2D compound 2 was synthesized in the mixed DMF/CH3OH solution.Porous compound 1 has some large solvent accessible voids while compound 2 has an impacted extended structure.关键词
杯芳烃/核簇/诱导作用/超分子组装Key words
Calixarene/ Metal cluster/ Inductive effect/ Supramolecular assembly分类
化学化工引用本文复制引用
毕研峰,廖伍平..Mn4-硫杂杯[4]芳烃单元的溶剂导向超分子组装[J].高等学校化学学报,2011,32(9):2175-2180,6.基金项目
国家自然科学基金(批准号:20971119)资助. （批准号:20971119）
