高等学校化学学报2011，Vol.32Issue(9)：2193-2197,5.
新型含丙腈基和咪唑基三脚架配体-银(Ⅰ)配合物的合成与结构
Syntheses and Structures of Silver( Ⅰ ) Complexes with New Tripodal Ligand Containing Propanenitrile and Imidazolyl Groups
摘要
Abstract
New complexes { [ AgL]X}n(X = BF4- , la; X = C1O4- ,1b) and { [ Ag(L)2] C1O4} n(2) were synthesized by the reactions of corresponding silver( I ) salt with new tripodal ligand 3,3'-[3-( lH-imidazol-l-yl)propylazanediyl]dipropanenitrile(L) under ligand to metal ratio of 1: 1 and 2:1, respectively, and their structures were determined by single crystal X-ray diffraction and electrospray mass spectrometry. Complexes la and lb have one-dimensional(1D) chain structure while complex 2 is mononuclear. The results show that the metal to ligand ratio has subtle influence on the structure of the complexes.关键词
银(Ⅰ)配合物/三脚架配体/晶体结构/电喷雾质谱Key words
Silver(Ⅰ) complex/ Tripodal ligand/ Crystal structure/ Electrospray mass spectrometry分类
化学化工引用本文复制引用
蔡凯,王媛媛,周鑫,亓昭鹏,王鹏,苏志,孙为银..新型含丙腈基和咪唑基三脚架配体-银(Ⅰ)配合物的合成与结构[J].高等学校化学学报,2011,32(9):2193-2197,5.基金项目
国家自然科学基金重点项目(批准号:20731004)资助. （批准号:20731004）
