高等学校化学学报2011，Vol.32Issue(9)：2198-2203,6.
两个新的含铜杂多钨酸盐的合成、晶体结构和电化学行为
Synthesis, Crystal Structure and Electrochemical Behavior of Two New Multi-copper-containing Heteropolyoxotungstates
摘要
Abstract
Two new multi-copper-containing polyoxotungstates [Cu(en)2(H2O)2][Cu(en)2]4[Cu(en)2 (H2O)][Cu4(H2O)2(SiW9O34)2] -7H2O(1) and [ Cu(en)2 ( H2O) ]2 [ Cu(en)2]4 [ CuSiW11O39 ]2 ? 7H2O(2) were hydrothermally synthesized. The diffraction analysis reveals that compound 1 represents the organic-inorganic hybrid based on the sandwich-type polyoxometalates linked by transition-metal coordination cations. The framework of 2 has a two-dimensional net-texture structure with vacancies in it, and the 2D layers are arranged in a parallel-staggering fashion to form a 3D supermolecules framework. It represents a 3D organic-inorganic hybrid based on the bimolecular Keggin polyoxometalates.关键词
多金属氧酸盐/晶体结构/电化学Key words
Polyoxometalate/ Crystal structure/ Electrochemistry分类
化学化工引用本文复制引用
梁畅,傅海,鹿颖,李阳光,王恩波..两个新的含铜杂多钨酸盐的合成、晶体结构和电化学行为[J].高等学校化学学报,2011,32(9):2198-2203,6.基金项目
国家自然科学基金(批准号:20901015)资助. （批准号:20901015）
