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梯度型LiNi1-2xCoxMnxO2材料的研究

朱靖 刘永光 王岭 赵艳琴

电源技术2011,Vol.35Issue(10):1218-1220,3.
电源技术2011,Vol.35Issue(10):1218-1220,3.

梯度型LiNi1-2xCoxMnxO2材料的研究

Study on LiNi1-2 xMnxCoxO2 concentration-gradient cathode material

朱靖 1刘永光 2王岭 1赵艳琴1

作者信息

  • 1. 河北联合大学化工学院,河北唐山063009
  • 2. 河北联合大学党委宣传部,河北唐山063009
  • 折叠

摘要

Abstract

The layered lithium nickel-rich oxides, concentration-gradient cathode material LiNi1_2xMnxCoxO2 was synthesized by carbonate co-precipitation method. The material was characterized by XRD and SEM. The results show that the prepared powder is a typical α-NaFeO2 layered structure and constitutes of small homogenous particles (100-400 nm). The prepared material achieves a high specfic capacity of 173.2 mAh/g and retains 92% of this capacity after 30 charge-discharge cycles. The steady-state reversible specfic capacities of 173.2.1 mAh/g at 0.5 C, 168.8 mAh/g at 1 C, 147 mAh/g at 2 C and 108 mAh/g at 5 C were achieved within the cut off voltage limits of 2.75 Vand 4.6 V at 20 ℃, which exhibited good rate capability.

关键词

锂离子电池/浓度梯度型正极材料/碳酸盐共沉淀法/倍率循环性能

Key words

lithium-ion batteries/concentration-gradient cathode material/cycling performance/rate capability

分类

信息技术与安全科学

引用本文复制引用

朱靖,刘永光,王岭,赵艳琴..梯度型LiNi1-2xCoxMnxO2材料的研究[J].电源技术,2011,35(10):1218-1220,3.

基金项目

河北省教育厅计划项目(2010288) (2010288)

唐山市科学技术研究与发展指导计划(09130204c) (09130204c)

河北理工大学科学研究基金资助项目 ()

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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