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KOH溶液中添加剂影响锌电化学性能的研究

林海斌 洪淑娜 梁曼 周合兵 李伟善

电源技术2011,Vol.35Issue(10):1227-1230,4.
电源技术2011,Vol.35Issue(10):1227-1230,4.

KOH溶液中添加剂影响锌电化学性能的研究

Effect of additives on electrochemical behaviors of Zn in KOH solution

林海斌 1洪淑娜 1梁曼 1周合兵 2李伟善2

作者信息

  • 1. 华南师范大学化学与环境学院,广东广州510006
  • 2. 广东高校电化学储能与发电技术重点实验室,广东广州510006
  • 折叠

摘要

Abstract

The electrochemical behaviors of Zn in 3 mol/L KOH solution containing different inhibitors were investigated by electrochemistry methods, scanning electron microscope and discharge of self-assembled batteries. The results show that either the individual additive or the composite additives can suppress the corrosion of zinc in 3 mol/L KOH solution. But the inhibition efficiency of the composite additives is higher than that of any individual additive because of the synergistic effect between sodium dodecyl benzene sulfonate (SDBS) and Bi (NO3)3. The effect can be carried out by increasing the adsorption of SDBS on the surface of zinc in the present of Bi (NO3)3. Furthermore, SDBS and Bi (NO3)3can bring into play their own advantages and make up the disadvantages of the each other in structure.

关键词

添加剂//缓蚀作用/协同效应

Key words

additives/zinc/corrosion inhibition effect/synergistic effect

分类

信息技术与安全科学

引用本文复制引用

林海斌,洪淑娜,梁曼,周合兵,李伟善..KOH溶液中添加剂影响锌电化学性能的研究[J].电源技术,2011,35(10):1227-1230,4.

基金项目

国家大学生创新性实验计划项目(101057408) (101057408)

广东省大学生创新性实验计划项目(1057410018) (1057410018)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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