石油化工2011，Vol.40Issue(7)：749-752,4.
中低温煤焦油加氢脱金属动力学研究
Kinetics for Hydrodemetalization of Coal Tar
摘要
Abstract
Hydrodemetalization kinetics of the coal tar from Erdos of Inner Mongolia was studied in a fixed - bed hydrogenation unit on the hydrogenation protection catalyst, the hydrodemetalization catalyst and the hydrocracking catalyst. The influences of reaction temperature, hydrogen partial pressure and liquid hourly space velocity (LHSV) on the hydrodemetalization were investigated. The kintics model for the hydrodemetalization of the coal tar was established. The experimental data were fitted by the Levenberg-Marquardt method. The result indicated that the hydrodemetalization was a 1.2 order reaction and its activation energy was 53. 896 kJ/mol, which was similar to hydrodemetalization of residual oil. The order of the parameters affecting the hydrodemetalization was; LHSV > reaction temperature > hydrogen partial pressure. The model was verified by the experimental data and all the relative errors were less than 2.1%.关键词
煤焦油/加氢脱金属催化剂/加氢保护/加氢裂化/动力学模型Key words
coal tar/hydrodemetalization catalyst/hydrogenation protection/hydrocracking/kinetics model分类
能源科技引用本文复制引用
马伟,李冬,李稳宏,雷雨辰,滕家辉,李琳..中低温煤焦油加氢脱金属动力学研究[J].石油化工,2011,40(7):749-752,4.基金项目
陕西省“13115”科技创新工程重大科技专项项目(2008ZDKG-50):2010陕西省“13115”科技创新工程项目(2010ZDKG42) （2008ZDKG-50）
陕西省自然科学基金项目(2010JM2002) （2010JM2002）
西安市科技局创新支撑计划项目(CXY1021) （CXY1021）
陕西省教育厅2010年产业化培育项目(2010JC23) （2010JC23）
陕西省教育厅自然科学基金项目(2010JK874) （2010JK874）
榆林市科技计划项目 （）
西北大学科学研究基金项目(09YZZ50) （09YZZ50）
西北大学研究生创新基金项目(09NW06). （09NW06）
