石油化工2011，Vol.40Issue(6)：667-672,6.
陕北中低温煤焦油的分离与GC-MS分析
Separation and GC-MS Analysis of Shanbei Low Temperature Coal Tar
摘要
Abstract
The light tar (L-tar) and heavy tar (H-tar) from Shanbei low temperature coal tar were separated by ultrasonic extraction and Soxhlet extraction to obtain petroleum ether fraction in L-tar (P-L-tarr) and petroleum ether fraction in H-tar ( P-H-tar), which could be analyzed by gas chromatography-mass spectrometry (GC-MS). The GC-MS analyses showed that P-L-tar and P-H-tar contained 295 compounds and 302 compounds respectively, which were mainly long-chain alkanes,phenols, naphthalenes, as well as a small amount of oxygen compounds and nitrogen compounds. Mass fractions of long-chain alkanes and phenols in P-L-tar are 42.43% and 18. 28% , and their mass fractions in P-H-tar are 21.53% and 36. 80% , respectively. The mass fraction of m-cresol in P-H-tar reaches 6.72%.关键词
中低温煤焦油/超声萃取/索氏萃取/气相色谱-质谱分析/酚类化合物Key words
low temperature coal tar/ultrasonic extraction/Soxhlet extraction/gas chromatography-mass spectrometry analysis/phenolic compound分类
化学工程引用本文复制引用
孙鸣,冯光,王汝成,徐龙,杨艳红,马晓迅..陕北中低温煤焦油的分离与GC-MS分析[J].石油化工,2011,40(6):667-672,6.基金项目
国家科技支撑项目(2009 BAA20 B02) （2009 BAA20 B02）
陕西省重大科技创新项目(2009ZKC04-06) （2009ZKC04-06）
陕西省科学技术研究发展计划项目(2010K01-082) （2010K01-082）
国家自然科学青年基金项目(NSFC21006078). （NSFC21006078）
