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羟基磷灰石含量对纳米粒子-聚己内酯复合材料性能的影响

陈广美 黄毅萍

安徽大学学报(自然科学版)2011,Vol.35Issue(5):73-79,7.
安徽大学学报(自然科学版)2011,Vol.35Issue(5):73-79,7.

羟基磷灰石含量对纳米粒子-聚己内酯复合材料性能的影响

Effect of the HA content on the properties of nanoparticle-polycaprolactone composites

陈广美 1黄毅萍2

作者信息

  • 1. 安徽建筑工业学院材料与化学工程学院,安徽合肥230601
  • 2. 安徽大学化学化工学院,安徽合肥230039
  • 折叠

摘要

Abstract

Hydroxyapatite nanoparticles ( HA) were synthesized by hydrothermal method. HA was dispersed in caprolactone and induced the ring-opening polymerization to prepare the nanoparticle-polymer composites. The effect of the HA content on the properties of the composites was discussed by NMR, DSC, XRD, PLM and mechanical measurements. Polymeric degree of PCL decreased with the increasing of HA content in composites and the agglomerate of the nano-particles existed in composites when the HA content was higher. As the HA was 5wt% in the raw materials, the strain at failure, tensile strength and compressive modulus arrived the highest value. When the content of HA was under 20wt% , the elastic modulus of the composites increased with the increasing of HA content .

关键词

纳米羟基磷灰石/聚己内酯/复合材料/结晶度/力学性能

Key words

nano-hydroxyapatite/ polycaprolactone/ composite/ crystallinity/ mechanical property

分类

化学化工

引用本文复制引用

陈广美,黄毅萍..羟基磷灰石含量对纳米粒子-聚己内酯复合材料性能的影响[J].安徽大学学报(自然科学版),2011,35(5):73-79,7.

基金项目

安徽省教育厅自然科学基金重点项目资助(KJ2009A024Z) (KJ2009A024Z)

安徽省自然科学基金资助项目(070414193) (070414193)

安徽大学学报(自然科学版)

OA北大核心CSTPCD

1000-2162

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